Synthesis of Cu 2 O micro/nanocrystals for catalytic combustion of high-concentration CO: The crucial role of glucose.

Cubic Cu ₂ O micro/nanocrystals were successfully synthesized by liquid-phase reduction using copper salt of CuSO ₄ or CuCl ₂ ·2H ₂ O, and glucose or ascorbic acid as reducing agent, respectively. The activity of the catalysts was evaluated by light-off curves of CO self-sustained catalytic combustion via temperature-programmed oxidation of CO (CO-TPO), with the results showing the activity of catalysts following the order of Cu ₂ O-Cl-GLU > Cu ₂ O-S-GLU > Cu ₂ O-S-AA > Cu ₂ O-Cl-AA, (Cl denotes CuCl ₂ ·2H ₂ O, GLU denotes glucose, S denotes CuSO ₄ and AA denotes ascorbic acid, respectively), corresponding to the ignition temperature of 109 °C, 122 °C, 137 °C and 186 °C, respectively. The crystal structure, elemental valence, morphology and redox property of the prepared catalysts were analyzed by using various characterization techniques. Combined with in situ infrared spectrum, the CO self-sustained catalytic combustion over Cu ₂ O catalysts mainly follows the Mars-van-Krevelen (M-v-K) mechanism: the adsorbed and activated CO reacts with lattice oxygen to yield CO ₂ and oxygen vacancy, and then the oxygen vacancy can be replenished by gaseous oxygen. Combined with catalytic performance of high-concentration CO, it is found that the catalysts prepared using glucose as reducing agent are more angular compared with ascorbic acid. The Cu ₂ O-Cl-GLU synthesized with glucose and CuCl ₂ ·2H ₂ O exhibits the best catalytic activity among all the catalysts tested, attributing to its more obvious edge and rough crystal surface. The unique structure of Cu ₂ O-Cl-GLU leads to the high exposure rate and coordination unsaturation of atoms on the cubic Cu ₂ O micro/nanocrystals that can improve the ability of activating gaseous O ₂ and low temperature reducibility, and consequently facilitating the catalytic activity.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
(Copyright © 2022 Elsevier Ltd. All rights reserved.)