Accelerated and natural carbonation of a municipal solid waste incineration (MSWI) fly ash mixture: Basic strategies for higher carbon dioxide sequestration and reliable mass quantification.

The carbonation of alkaline wastes is an interesting research field that may offer opportunities for CO ₂ reduction. However, the literature is mainly devoted to studying different waste sequestration capabilities, with lame attention to the reliability of the data about CO ₂ reduction, or to the possibilities to increase the amount of absorbed CO ₂ . In this work, for the first time, the limitation of some methods used in literature to quantify the amount of sequestered CO ₂ is presented, and the advantages of using suitable XRD strategies to evaluate the crystalline calcium carbonate phases are demonstrated. In addition, a zero-waste approach, aiming to stabilize the waste by coupling the use of by-products and the possibility to obtain CO ₂ sequestration, was considered. In particular, for the first time, the paper investigates the differences in natural and accelerated carbonation (NC and AC) mechanisms, occurring when municipal solid waste incineration (MSWI) fly ash is stabilized by using the bottom ash with the same origin, and other by-products. The stabilization mechanism was attributed to pozzolanic reactions with the formation of calcium silicate hydrates or calcium aluminate hydrate phases that can react with CO ₂ to produce calcium carbonate phases. The work shows that during the AC, crystalline calcium carbonate was quickly formed by the reaction of Ca(OH) ₂ and CaClOH with CO ₂ . On the contrary, in NC, carbonation occurred due to reactions also with the amorphous Ca. The sequestration capability of this technology, involving the mixing of waste and by-products, is up to 165 gCO ₂ /Kg MSWI FA, which is higher than the literature data.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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