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Protoboration of Alkynes and Miyaura Borylation Catalyzed by Low Loadings of Palladium.

Authors :
Xu L
Dong Z
Zhang Q
Deng N
Li SY
Xu HJ
Source :
The Journal of organic chemistry [J Org Chem] 2022 Nov 04; Vol. 87 (21), pp. 14879-14888. Date of Electronic Publication: 2022 Oct 12.
Publication Year :
2022

Abstract

The versions of Miyaura borylation and protoboration of alkynes catalyzed by low loadings of palladium (400 mol ppm = 0.04 mol %) have been developed. These transformations have a broad substrate scope, good functional-group compatibility, and gram-scale synthetic ability.

Subjects

Subjects :
Catalysis
Palladium
Alkynes

Details

Language :
English
ISSN :
1520-6904
Volume :
87
Issue :
21
Database :
MEDLINE
Journal :
The Journal of organic chemistry
Publication Type :
Academic Journal
Accession number :
36223839
Full Text :
https://doi.org/10.1021/acs.joc.2c01649