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State-to-state photodissociation dynamics of CO 2 at 157 nm.
- Source :
-
Physical chemistry chemical physics : PCCP [Phys Chem Chem Phys] 2022 Oct 19; Vol. 24 (40), pp. 25018-25024. Date of Electronic Publication: 2022 Oct 19. - Publication Year :
- 2022
-
Abstract
- State-to-state photodissociation of CO <subscript>2</subscript> ( v <subscript>2</subscript> = 0 and 1) at 157 nm via the O( <superscript>1</superscript> D) + CO( X <superscript>1</superscript> Σ <superscript>+</superscript> ) channel was studied by using the sliced velocity map imaging technique. Both the O( <superscript>1</superscript> D) and CO( X <superscript>1</superscript> Σ <superscript>+</superscript> ) products were detected by (2 + 1) resonance enhanced multiphoton ionization (REMPI). Detection of CO via the B <superscript>1</superscript> Σ <superscript>+</superscript> ←← X <superscript>1</superscript> Σ <superscript>+</superscript> transition allowed ro-vibrational state-selective detection, and combined with imaging, the fragment energy and angular distributions have been derived. For CO( v = 0 and 1| j ) products from the CO <subscript>2</subscript> ( v <subscript>2</subscript> = 0) molecule, the angular distributions of low- j CO display positive anisotropic parameters (about 0.8); with j increasing, the product anisotropic parameters gradually reduce to zero. While for CO( v = 0 and 1| j ) products from the vibrational excited CO <subscript>2</subscript> ( v <subscript>2</subscript> = 1) molecule, the angular distributions of low- j CO also display positive anisotropic parameters; with j increasing, the product anisotropic parameters first decrease to zero and then become negative (about -0.5). Experimental results show that the observed variation of the product angular distribution with the rotational quantum number of CO is consistent with trends predicted by a classical model for non-axial fragment recoil. The results support advanced theoretical predictions of a predominantly parallel transition to the bent 2 <superscript>1</superscript> A' excited state of CO <subscript>2</subscript> , where bending introduces torque during the direct dissociation process.
Details
- Language :
- English
- ISSN :
- 1463-9084
- Volume :
- 24
- Issue :
- 40
- Database :
- MEDLINE
- Journal :
- Physical chemistry chemical physics : PCCP
- Publication Type :
- Academic Journal
- Accession number :
- 36218045
- Full Text :
- https://doi.org/10.1039/d2cp04020d