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Stepwise structure evolution from 2D cluster-based frameworks to silver(I) clusters.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2022 Oct 25; Vol. 58 (85), pp. 11985-11988. Date of Electronic Publication: 2022 Oct 25. - Publication Year :
- 2022
-
Abstract
- A pair of 2D chiral frameworks, R-Ag5-1 and S-Ag5-1, with orange fluorescence were successfully synthesized. They were transformed to a thermodynamically favored denser stacking, R-Ag5-3 and S-Ag5-3, accompanied by a change in the luminescence and activating the CPL signal. The capture and structural determination of the intermediates (R-Ag5-2 and S-Ag5-2) reveal that the coordination instability of Na <superscript>+</superscript> ions is the main cause of this transition.
- Subjects :
- Ions chemistry
Silver chemistry
Luminescence
Subjects
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 58
- Issue :
- 85
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 36217883
- Full Text :
- https://doi.org/10.1039/d2cc04623g