Back to Search
Start Over
Fully inkjet-printed paper-based Pb 2+ optodes for water analysis without interference from the chloramine disinfectant.
- Source :
-
Analytical and bioanalytical chemistry [Anal Bioanal Chem] 2022 Nov; Vol. 414 (26), pp. 7585-7595. Date of Electronic Publication: 2022 Aug 23. - Publication Year :
- 2022
-
Abstract
- We developed a paper-based colorimetric sensor for facile and cost-effective detection of Pb <superscript>2+</superscript> in drinking and environmental water samples. The Pb <superscript>2+</superscript> ion-selective optodes are fabricated by inkjet printing of ionophore, chromoionophore, and ion exchanger on cellulose paper. Pb <superscript>2+</superscript> in water samples induces deprotonation of the pH chromoionophore and changes the optode color, which is acquired and analyzed by a smartphone. The paper-based optode without any plasticizer or polymer has a dynamic range and selectivity comparable to those of traditional optodes using PVC polymer and/or plasticizer. Furthermore, the response time of the plasticizer/polymer-free paper-based optode is much shorter than those of plasticized PVC-based optodes on paper and glass (5 min vs. 15 and 50 min). Moreover, the plasticizer/polymer-free optode preserves the water-wicking capability of porous cellulose paper, allowing for the design of pump-free microfluidic devices. Chloramine, a widely used disinfectant in drinking water, was found to be a strong and generic interference species for heavy metal ion detection via ion-selective optodes. A fully inkjet-printed lateral-flow paper-based device consisting of a sodium thiosulfate-based chloramine elimination zone and a plasticizer/polymer-free sensing zone was designed for Pb <superscript>2+</superscript> detection in tap water disinfected by chloramine. The dynamic range of the Pb <superscript>2+</superscript> sensor may be shifted from the current 10 <superscript>-6</superscript> to 10 <superscript>-5</superscript>  M to lower concentrations by using stronger ionophores, but this work lays a foundation for the design of paper-based heavy metal ion sensors without detrimental interference from disinfectants.<br /> (© 2022. Springer-Verlag GmbH Germany, part of Springer Nature.)
Details
- Language :
- English
- ISSN :
- 1618-2650
- Volume :
- 414
- Issue :
- 26
- Database :
- MEDLINE
- Journal :
- Analytical and bioanalytical chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 35997814
- Full Text :
- https://doi.org/10.1007/s00216-022-04286-y