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2D crystal structure and anisotropic magnetism of GdAu 6.75-x Al 0.5+x (x ≈ 0.54).
- Source :
-
Scientific reports [Sci Rep] 2022 Jul 30; Vol. 12 (1), pp. 13141. Date of Electronic Publication: 2022 Jul 30. - Publication Year :
- 2022
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Abstract
- Exploration of the gold-rich part of the ternary Gd-Au-Al system afforded the intermetallic compound GdAu <subscript>6.75-x</subscript> Al <subscript>0.5+x</subscript> (x ≈ 0.54) which was structurally characterized by single crystal X-ray diffraction (Pnma, a = 18.7847(4) Å, b = 23.8208(5) Å, c = 5.3010(1) Å). GdAu <subscript>6.75-x</subscript> Al <subscript>0.5+x</subscript> crystallizes in a previously unknown structure type featuring layers of Gd <subscript>2</subscript> (Au, Al) <subscript>29</subscript> and Gd <subscript>2</subscript> (Au, Al) <subscript>28</subscript> clusters which are arranged as in a close-packing parallel to the ac plane. The Gd substructure corresponds to slightly corrugated 3 <superscript>6</superscript> nets (d <subscript>Gd-Gd</subscript> = 5.30-5.41 Å) which are stacked on top of each other along the b direction with alternating short (5.4, 5.6 Å, within layers) and long distances (6.4 Å, between layers). The title compound has been discussed with respect to a quasicrystal approximant (1/1 AC) GdAu <subscript>5.3</subscript> Al in the same system. The magnetic properties of GdAu <subscript>6.75-x</subscript> Al <subscript>0.5+x</subscript> were found to be reminiscent to those of some ternary ACs, with sharp peaks in the temperature dependent magnetization, and metamagnetic-like transitions. The material becomes antiferromagnetic below 25 K; magnetometry results suggest that the antiferromagnetic state is composed of ferromagnetic ac planes, coupled antiferromagnetically along the b direction.<br /> (© 2022. The Author(s).)
Details
- Language :
- English
- ISSN :
- 2045-2322
- Volume :
- 12
- Issue :
- 1
- Database :
- MEDLINE
- Journal :
- Scientific reports
- Publication Type :
- Academic Journal
- Accession number :
- 35907933
- Full Text :
- https://doi.org/10.1038/s41598-022-17068-4