High-Performance 1 cm 2 Perovskite-Organic Tandem Solar Cells with a Solvent-Resistant and Thickness-Insensitive Interconnecting Layer.

Organic solar cells (OSCs) and perovskite solar cells (PVSCs) are promising candidates for next-generation thin film photovoltaic technologies. The integration of OSCs with PVSCs in tandem devices is now attracting significant attention due to their similar fabrication procedures and the potential to afford a higher device performance. Here, a thickness-insensitive and solvent-resistant interconnecting layer is developed to efficiently connect perovskite and organic subcells with low contact resistance. The resultant perovskite-organic tandem devices maintain high efficiencies over a wide thickness range of the interconnecting layer, from ∼20 nm to ∼50 nm, providing an easily fabricated, solvent-resistant platform to integrate perovskite and organic active layers with low-temperature solution processing techniques. The tandem devices containing an ultrathin PVSC and a typical non-fullerene OSC give a maximum efficiency of 19.2%, which is much higher than those of the single-junction devices. Moreover, highly reproducible 1 cm ² perovskite-organic tandem devices are achieved using the thickness-insensitive and solvent-resistant interconnecting layer, and an efficiency of 17.8% is realized. These 1 cm ² tandem solar cells are used successfully in solar-to-hydrogen systems to afford a solar-to-fuel conversion efficiency of 11.2%. Overall, these advances represent significant progress in the design of ultrathin and facile solution processed perovskite-organic tandem solar cells.