Kinetics and Adsorption Isotherms of Amine-Functionalized Magnesium Ferrite Produced Using Sol-Gel Method for Treatment of Heavy Metals in Wastewater.

This study is focused on the kinetics and adsorption isotherms of amine-functionalized magnesium ferrite (MgFe ₂ O ₄ ) for treating the heavy metals in wastewater. A sol-gel route was adopted to produce MgFe ₂ O ₄ nanoparticles. The surfaces of the MgFe ₂ O ₄ nanoparticles were functionalized using primary amine (ethanolamine). The surface morphology, phase formation, and functionality of the MgFe ₂ O ₄ nano-adsorbents were studied using the SEM, UV-visible, FTIR, and TGA techniques. The characterized nanoparticles were tested on their ability to adsorb the Pb ²⁺ , Cu ²⁺ , and Zn ²⁺ ions from the wastewater. The kinetic parameters and adsorption isotherms for the adsorption of the metal ions by the amine-functionalized MgFe ₂ O ₄ were obtained using the pseudo-first-order, pseudo-second-order, Langmuir, and Freundlich models. The pseudo-second order and Langmuir models best described the adsorption kinetics and isotherms, implying strong chemisorption via the formation of coordinative bonds between the amine groups and metal ions. The Langmuir equation revealed the highest adsorption capacity of 0.7 mmol/g for the amine-functionalized MgFe ₂ O ₄ nano-adsorbents. The adsorption capacity of the nanoadsorbent also changed with the calcination temperature. The MgFe ₂ O ₄ sample, calcined at 500 °C, removed the most of the Pb ²⁺ (73%), Cu ²⁺ (59%), and Zn ²⁺ (62%) ions from the water.