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C-H Arylation in the Synthesis of π-Conjugated Polymers.

Authors :
Suraru SL
Lee JA
Luscombe CK
Source :
ACS macro letters [ACS Macro Lett] 2016 Jun 21; Vol. 5 (6), pp. 724-729. Date of Electronic Publication: 2016 May 27.
Publication Year :
2016

Abstract

C-H activation reactions have allowed us to react traditionally chemically inert bonds in molecules to develop new methods for cross-coupling reactions. This type of reactivity can be applied to conjugated polymer materials in an effort to improve existing synthetic difficulties including harsh reaction conditions, multiple monomer functionalization steps, and organometallic reagent waste. In this Viewpoint, we highlight some of the encouraging advances in direct arylation polymerization (DArP) as well as ongoing challenges for future improvement and utility.

Details

Language :
English
ISSN :
2161-1653
Volume :
5
Issue :
6
Database :
MEDLINE
Journal :
ACS macro letters
Publication Type :
Academic Journal
Accession number :
35614668
Full Text :
https://doi.org/10.1021/acsmacrolett.6b00279