A new class of organoplatinum-based DFNS for the production of cyclic carbonates from olefins and CO 2 .

Authors :: Abassian M
Zhiani R
Motavalizadehkakhky A
Eshghi H
Mehrzad J
Source :: RSC advances [RSC Adv] 2020 Apr 16; Vol. 10 (26), pp. 15044-15051. Date of Electronic Publication: 2020 Apr 16 (Print Publication: 2020).
Publication Year :: 2020
Abstract: We studied the potential application of an efficient, reusable, and easily recoverable catalyst of dendritic fibrous nanosilica (DFNS)-supported platinum(ii) complexes (DFNS/Pt(ii) NPs) to form cyclic carbonates in the presence of epoxides by converting carbon dioxide. Cyclic carbonates from epoxides and carbon dioxide is proposed as the most appropriate way to synthesis this C1 building block. We performed FE-SEM, TEM, TGA, BET, VSM, and ICP-MS to thoroughly characterize DFNS/Pt(ii) NPs.<br />Competing Interests: There are no conflicts to declare.<br /> (This journal is © The Royal Society of Chemistry.)

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