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Palladium-catalyzed regioselective hydrosulfonylation of allenes with sulfinic acids.
- Source :
-
RSC advances [RSC Adv] 2022 Mar 18; Vol. 12 (14), pp. 8443-8448. Date of Electronic Publication: 2022 Mar 18 (Print Publication: 2022). - Publication Year :
- 2022
-
Abstract
- An atom-economic method of preparing allylic sulfones via hydrosulfonylation of allenes with sulfinic acids under Pd(0)-catalysis was reported. This process has a high degree of regio- and stereoselectivity, and provides the target product with a moderate to excellent yield. A wide range of nitrogen- or oxygen-containing linear E -allylic sulfones have been synthesized. With the support of experimental research, a possible mechanism was proposed.<br />Competing Interests: There are no conflicts to declare.<br /> (This journal is © The Royal Society of Chemistry.)
Details
- Language :
- English
- ISSN :
- 2046-2069
- Volume :
- 12
- Issue :
- 14
- Database :
- MEDLINE
- Journal :
- RSC advances
- Publication Type :
- Academic Journal
- Accession number :
- 35424818
- Full Text :
- https://doi.org/10.1039/d1ra09036d