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Fabrication and Characterization of Highly Efficient As-Synthesized WO 3 /Graphitic-C 3 N 4 Nanocomposite for Photocatalytic Degradation of Organic Compounds.

Authors :
Hussien MSA
Bouzidi A
Abd-Rabboh HSM
Yahia IS
Zahran HY
Abdel-Wahab MS
Alharbi W
Awwad NS
Ibrahim MA
Source :
Materials (Basel, Switzerland) [Materials (Basel)] 2022 Mar 28; Vol. 15 (7). Date of Electronic Publication: 2022 Mar 28.
Publication Year :
2022

Abstract

The incorporation of tungsten trioxide (WO <subscript>3</subscript> ) by various concentrations of graphitic carbon nitride (g-C <subscript>3</subscript> N <subscript>4</subscript> ) was successfully studied. X-ray diffraction (XRD), Scanning Electron Microscope (SEM), and Diffused Reflectance UV-Vis techniques were applied to investigate morphological and microstructure analysis, diffused reflectance optical properties, and photocatalysis measurements of WO <subscript>3</subscript> /g-C <subscript>3</subscript> N <subscript>4</subscript> photocatalyst composite organic compounds. The photocatalytic activity of incorporating WO3 into g-C <subscript>3</subscript> N <subscript>4</subscript> composite organic compounds was evaluated by the photodegradation of both Methylene Blue (MB) dye and phenol under visible-light irradiation. Due to the high purity of the studied heterojunction composite series, no observed diffraction peaks appeared when incorporating WO <subscript>3</subscript> into g-C <subscript>3</subscript> N <subscript>4</subscript> composite organic compounds. The particle size of the prepared composite organic compound photocatalysts revealed no evident influence through the increase in WO <subscript>3</subscript> atoms from the SEM characteristic. The direct and indirect bandgap were recorded for different mole ratios of WO <subscript>3</subscript> /g-C <subscript>3</subscript> N <subscript>4,</subscript> and indicated no apparent impact on bandgap energy with increasing WO <subscript>3</subscript> content in the composite photocatalyst. The composite photocatalysts' properties better understand their photocatalytic activity degradations. The pseudo-first-order reaction constants (K) can be calculated by examining the kinetic photocatalytic activity.

Details

Language :
English
ISSN :
1996-1944
Volume :
15
Issue :
7
Database :
MEDLINE
Journal :
Materials (Basel, Switzerland)
Publication Type :
Academic Journal
Accession number :
35407814
Full Text :
https://doi.org/10.3390/ma15072482