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Fac -to- mer isomerization triggers hydride transfer from Mn(I) complex fac -[(dppm)Mn(CO) 3 H].
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2022 Apr 19; Vol. 58 (32), pp. 5017-5020. Date of Electronic Publication: 2022 Apr 19. - Publication Year :
- 2022
-
Abstract
- Low-temperature IR and NMR studies combined with DFT calculations revealed the mechanistic complexity of apparently simple reactions between Mn(I) complex fac -[(dppm)Mn(CO) <subscript>3</subscript> H] and Lewis acids (LA = Ph <subscript>3</subscript> C <superscript>+</superscript> , B(C <subscript>6</subscript> F <subscript>5</subscript> ) <subscript>3</subscript> ) involving the formation of so-far elusive meridional hydride species mer -[(dppm)Mn(CO) <subscript>3</subscript> H⋯LA] and unusual dearomatization of the Ph <subscript>3</subscript> C <superscript>+</superscript> cation upon hydride transfer.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 58
- Issue :
- 32
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 35373227
- Full Text :
- https://doi.org/10.1039/d2cc00999d