A novel route to the synthesis of α-Fe2O3@C@SiO2/TiO2 nanocomposite from the metal-organic framework as a photocatalyst for water treatment.

In this study, an attempt was made to synthesize metal-organic frameworks (MOFs) based magnetic iron particles as photocatalysts for textile dye wastewater. Improvement strategy was a novel two-step dry method without using conventional methods to eliminate the consumption of chemical reagents. First, the heterogeneous photocatalyst of Fe-MOFs derived magnetic carbon nanocomposite with carboxylic acid surface functional groups (Fe@C-COOH) was achieved. Next, the α-Fe ₂ O ₃ @C@SiO ₂ /TiO ₂ was successfully synthesized followed by a sol-gel method to coat the SiO ₂ shell and a solvothermal method to coat the surface of the intermediate TiO ₂ particles. The as-synthesized nanocomposite materials were characterized and physicochemical analytical equipment. Further, the investigation on magnetic photocatalytic nanocomposite α-Fe ₂ O ₃ @C@SiO ₂ /TiO ₂ performance of dye degradation and photocatalytic activity on Reactive yellow 145 (RY145), using as an indicator was conducted. The as-synthesized nanocomposite particles were characterized using X-ray powder diffraction (XRD), thermogravimetric analysis (TGA), Fourier-transform infrared spectroscopy (FT-IR), vibrating sample magnetometer (VSM), X-ray energy dispersive spectroscopy (EDX), and scanning electron microscopy (SEM) techniques. The structural characterization of the as-synthesized materials proved that these methods generate oxygen-containing functional groups, such as, -OH, -CO, and -COOH, which increases the polarity and hydrophilicity of the photocatalyst. The photocatalytic oxidation of RY145 dye under UVc light was discussed by the apparent first-order reaction rate and the kinetic model of the Langmuir-Hinshelwood followed a better fitting. The optimal performance of the composite is at pH = 2, 15 mg/100 mL of photocatalyst dose, 150 mg/L concentration of the dye RY145 at 25 °C temperature under UVc lamp irradiation for 90 min, and with the apparent reaction rate constant was 0.0165 min ^-1 . The thermodynamic analysis of activation parameters computed by the Eyring model and based on transition state theory (TST), an endothermic reaction with a positive value for Δ ^‡ H ^o (50.16 kJ mol ^-1 ) and a negative value for Δ ^‡ S ^o (-153 J/mol K) both contribute toward achieving positive values for Δ ^‡ G ^o and a nonspontaneous process. The proposed α-Fe ₂ O ₃ @C@SiO ₂ /TiO ₂ demonstrated a high capability of photocatalytic degradation up to 97% after five successive cycles at the optimal condition compared to that of Fe ₃ O ₄ @C (18.74%) and Fe@C-COOH (77.9%) without reusability.
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