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Dynamic [1]rotaxanes via a reversible covalent bond and host-guest anion recognition.

Authors :
Del Mauro A
Kokan Z
Šindelář V
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2022 Mar 18; Vol. 58 (23), pp. 3815-3818. Date of Electronic Publication: 2022 Mar 18.
Publication Year :
2022

Abstract

Bambus[6]uril-based [1]rotaxanes were formed quantitatively, utilizing a bis(acyloxy)iodate(I) reversible covalent bond and host-guest anion recognition. These novel [1]rotaxanes exhibited a dynamic nature facilitating carboxylate component exchange reactions in acetonitrile.

Details

Language :
English
ISSN :
1364-548X
Volume :
58
Issue :
23
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
35234240
Full Text :
https://doi.org/10.1039/d2cc00779g