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Deoxygenative C-S Bond Coupling with Sulfinates via Nickel/Photoredox Dual Catalysis.
- Source :
-
Organic letters [Org Lett] 2022 Mar 11; Vol. 24 (9), pp. 1865-1870. Date of Electronic Publication: 2022 Feb 28. - Publication Year :
- 2022
-
Abstract
- The C-S bond formation from aryl halides and thiols has been well established under various catalytic systems. In this work, user-friendly sulfinates have been exploited as an efficient sulfenylating reagent in the C-S couplings through visible-light-induced photo/nickel dual catalysis under base- and external reductant-free conditions. A large number of aryl sulfide products were accessed with high selectivity and high tolerance of various functionalities.
- Subjects :
- Catalysis
Oxidation-Reduction
Sulfhydryl Compounds
Light
Nickel chemistry
Subjects
Details
- Language :
- English
- ISSN :
- 1523-7052
- Volume :
- 24
- Issue :
- 9
- Database :
- MEDLINE
- Journal :
- Organic letters
- Publication Type :
- Academic Journal
- Accession number :
- 35225630
- Full Text :
- https://doi.org/10.1021/acs.orglett.2c00478