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Asymmetric Henry Reaction of Trifluoromethyl Enones with Nitromethane Using a N,N-Dibenzyl Diaminomethylenemalononitrile Organocatalyst.
- Source :
-
Chemistry, an Asian journal [Chem Asian J] 2022 Feb 14; Vol. 17 (4), pp. e202101299. Date of Electronic Publication: 2022 Jan 12. - Publication Year :
- 2022
-
Abstract
- A novel N,N-dibenzyl diaminomethylenemalononitrile organocatalyst efficiently promoted asymmetric Henry reactions of trifluoromethyl enones with nitromethane, affording corresponding highly functionalized products in high yields with excellent enantioselectivities (up to 90% ee). This study is the first to report the successful example of the asymmetric 1,2-additions of nitromethane to trifluoromethyl enones.<br /> (© 2021 Wiley-VCH GmbH.)
Details
- Language :
- English
- ISSN :
- 1861-471X
- Volume :
- 17
- Issue :
- 4
- Database :
- MEDLINE
- Journal :
- Chemistry, an Asian journal
- Publication Type :
- Academic Journal
- Accession number :
- 34927372
- Full Text :
- https://doi.org/10.1002/asia.202101299