Visible light-induced oxidative N -dealkylation of alkylamines by a luminescent osmium(vi) nitrido complex.

Authors :: Xiang J
Peng M
Pan Y
Luo LJ
Cheng SC
Jin XX
Yiu SM
Man WL
Ko CC
Lau KC
Lau TC
Source :: Chemical science [Chem Sci] 2021 Oct 09; Vol. 12 (43), pp. 14494-14498. Date of Electronic Publication: 2021 Oct 09 (Print Publication: 2021).
Publication Year :: 2021
Abstract: N -Dealkylation of amines by metal oxo intermediates (M[double bond, length as m-dash]O) is related to drug detoxification and DNA repair in biological systems. In this study, we report the first example of N -dealkylation of various alkylamines by a luminescent osmium(vi) nitrido complex induced by visible light.<br />Competing Interests: There are no conflicts to declare.<br /> (This journal is © The Royal Society of Chemistry.)

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