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Unexpected formation of a dodecanuclear {CoII6CuII6} nanowheel under ambient conditions: magneto-structural correlations.

Authors :
do Pim WD
Silva IF
da Silva Júnior EN
Stumpf HO
Oliveira WXC
Pedroso EF
Pinheiro CB
Journaux Y
Fantuzzi F
Krummenacher I
Braunschweig H
Engels B
Cano J
Julve M
Pereira CLM
Source :
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2021 Sep 21; Vol. 50 (36), pp. 12430-12434. Date of Electronic Publication: 2021 Sep 21.
Publication Year :
2021

Abstract

We report the unique heterobimetallic dodecanuclear oxamate-based {CoII6CuII6} nanowheel obtained using an environmentally friendly synthetic protocol. The effective Hamiltonian methodology employed herein allows the rationalisation of magnetic isotropic or anisotropic metal clusters, being a significant advance for future studies of exciting properties only observed at low and ultralow temperatures.

Details

Language :
English
ISSN :
1477-9234
Volume :
50
Issue :
36
Database :
MEDLINE
Journal :
Dalton transactions (Cambridge, England : 2003)
Publication Type :
Academic Journal
Accession number :
34545875
Full Text :
https://doi.org/10.1039/d1dt02268g