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Zn 0.94 Mn 0.06 O for adsorption and photo-degradation of methyl orange dye under visible irradiation: Kinetics and isotherms study.
- Source :
-
Environmental research [Environ Res] 2022 Jan; Vol. 203, pp. 111833. Date of Electronic Publication: 2021 Aug 14. - Publication Year :
- 2022
-
Abstract
- Three photocatalyst-adsorbents consist of Zn <subscript>0.97</subscript> Mn <subscript>0.03</subscript> O, Zn <subscript>0.94</subscript> Mn <subscript>0.06</subscript> O, and Zn <subscript>0.92</subscript> Mn <subscript>0.08</subscript> O were synthesized by hydrothermal method and calcined at 800 °C. The structural and optical properties of the sample Zn <subscript>0.94</subscript> Mn <subscript>0.06</subscript> O were characterized by using XRD; TEM; SEM; EDS; DLS; and DRS. The surface of the sample Zn <subscript>0.94</subscript> Mn <subscript>0.06</subscript> O consists of nano-particles (<100 nm) and nano-holes (18.4 nm), also the band-gap of it was obtained 2.89 eV. Adsorption and photo-degradation of methyl orange (MO) dye was investigated in darkness and under visible light irradiation (200 W tungsten). The sample Zn <subscript>0.94</subscript> Mn <subscript>0.06</subscript> O showed the most decolorization efficiency in the shortest time, so that 0.15 g of it adsorbed and destroyed the MO dye molecules (99 ± 1 %) in 40 s under irradiation. The most adsorption capacity of Zn <subscript>0.94</subscript> Mn <subscript>0.06</subscript> O was obtained 30.06 mg/g and the mechanism of the dye adsorption was investigated by using BET analysis and zeta potential. Also the adsorption isotherm and kinetics were calculated for describing the adsorption of MO onto the Zn <subscript>0.94</subscript> Mn <subscript>0.06</subscript> O.<br /> (Copyright © 2021 Elsevier Inc. All rights reserved.)
- Subjects :
- Adsorption
Azo Compounds
Kinetics
Light
Zinc
Subjects
Details
- Language :
- English
- ISSN :
- 1096-0953
- Volume :
- 203
- Database :
- MEDLINE
- Journal :
- Environmental research
- Publication Type :
- Academic Journal
- Accession number :
- 34403667
- Full Text :
- https://doi.org/10.1016/j.envres.2021.111833