Valorization of Miscanthus × giganteus by γ-Valerolactone/H 2 O/FeCl 3 system toward efficient conversion of cellulose and hemicelluloses.

γ-Valerolactone (GVL), a biomass-derived green chemical, offers an environmentally responsible solvent for conversion of lignocellulose to high value-added chemicals. Herein, we report a two-step process for directly producing cellulosic residual, furfural and lignin from Miscanthus × giganteus (M. × giganteus) bypassing the isolation of xylose, which exhibits promising advantage in energy reduction. The optimized pretreatment (100 mM FeCl ₃ at 160 °C for 60 min) induced significant xylan removal (98.4%), resulting in rugged fibre surface, thus leading to the peak cellulose conversion of 99.3%. Furfural yield in the second step reached to 76.6% after 100 mM FeCl ₃ catalyzed GVL/H ₂ O treatment at 180 °C for 10 min without addition of any chemical. The extracted lignin showed representative structure (such as β-O-4', β-β' linkages) and medium molecular weight (4275.5 g/mol). 79.6% of furfural can be recovered by distillation. This study proposes a systematic and energy efficient approach for maximizing biomass utilization.
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