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Electrochemical phenothiazination of naphthylamines and its application in photocatalysis.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2021 Sep 04; Vol. 57 (68), pp. 8512-8515. Date of Electronic Publication: 2021 Aug 05. - Publication Year :
- 2021
-
Abstract
- N-Phenylphenothiazine as an inexpensive, highly reductive and oxygen tolerant organophotocatalyst has exhibited potential in various challenging photochemical transformations. Here we report a general and straightforward method to access structurally diverse N-phenylphenothiazine derivatives by means of a novel electrochemical tool. The introduction of a 2-naphthylamine moiety with an extended π-system and an amine group led to the variation of spectral characterization. Photochemical verification experiments demonstrated that the formed N-arylation products with good efficacy and chemo/site-control displayed competitive catalytic activity in challenging transformations.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 57
- Issue :
- 68
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 34351332
- Full Text :
- https://doi.org/10.1039/d1cc03276c