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Scalable High-Pressure Synthesis of sp 2 -sp 3 Carbon Nanoribbon via [4 + 2] Polymerization of 1,3,5-Triethynylbenzene.
- Source :
-
The journal of physical chemistry letters [J Phys Chem Lett] 2021 Aug 05; Vol. 12 (30), pp. 7140-7145. Date of Electronic Publication: 2021 Jul 23. - Publication Year :
- 2021
-
Abstract
- Pressure-induced polymerization of aromatics is an effective method to construct extended carbon materials, including the diamond-like nanothread and graphitic structures, but the reaction pressure of phenyl is typically around 20 GPa and too high to be applied for large-scale preparation. Here by introducing ethynyl to phenyl, we obtained a sp <superscript>2</superscript> -sp <superscript>3</superscript> carbon nanoribbon structure by compressing 1,3,5-triethynylbenzene (TEB), and the reaction pressure of phenyl was successfully decreased to 4 GPa, which is the lowest reaction pressure of aromatics at room temperature. Using experimental and theoretical methods, we figured out that the ethynylphenyl of TEB undergoes [4 + 2] dehydro-Diels-Alder (DDA) reaction with phenyl upon compression at an intermolecular C···C distance above 3.3 Å, which is much longer than those of benzene and acetylene. Our research suggested that the DDA reaction between ethynylphenyl and phenyl is a promising route to decrease the reaction pressure of aromatics, which allows the scalable high-pressure synthesis of nanoribbon materials.
Details
- Language :
- English
- ISSN :
- 1948-7185
- Volume :
- 12
- Issue :
- 30
- Database :
- MEDLINE
- Journal :
- The journal of physical chemistry letters
- Publication Type :
- Academic Journal
- Accession number :
- 34297574
- Full Text :
- https://doi.org/10.1021/acs.jpclett.1c01945