A polysaccharide from Lignosus rhinocerotis sclerotia: Self-healing properties and the effect of temperature on its rheological behavior.

This work investigated the self-healing properties of Lignosus rhinocerotis polysaccharide (LRP) and the effect of temperature on its rheological behavior. Dynamic sweep tests (strain sweep, frequency sweep, and time sweep) showed that the LRP/water system possessed self-healing properties due to the entangled network formed by hyperbranched LRP molecular chains. The flow activation energy of LRP solution calculated by Arrhenius equation was shown to decrease with increasing LRP concentration, indicating that LRP solution at higher concentration was less sensitive to temperature. Temperature ramp test exhibited that LRP had a glass transition temperature (T _g ) determined as 49.35 °C and the temperature effect was irreversible. Microrheological test revealed that the LRP aqueous solution can form a gel at room temperature with the concentration ≥ 20 mg/mL. This work provided a theoretical basis for the development of LRP-based self-healing materials and facilitated a deep understanding of the temperature effect on rheological behavior of LRP.
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