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Phase Transitions in the "Spinel-Layered" Li 1+x Ni 0.5 Mn 1.5 O 4 (x = 0, 0.5, 1) Cathodes upon (De)lithiation Studied with Operando Synchrotron X-ray Powder Diffraction.
- Source :
-
Nanomaterials (Basel, Switzerland) [Nanomaterials (Basel)] 2021 May 21; Vol. 11 (6). Date of Electronic Publication: 2021 May 21. - Publication Year :
- 2021
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Abstract
- "Spinel-layered" Li <subscript>1+ x </subscript> Ni <subscript>0.5</subscript> Mn <subscript>1.5</subscript> O <subscript>4</subscript> ( x = 0, 0.5, 1) materials are considered as a cobalt-free alternative to currently used positive electrode (cathode) materials for Li-ion batteries. In this work, their electrochemical properties and corresponding phase transitions were studied by means of synchrotron X-ray powder diffraction (SXPD) in operando regime. Within the potential limit of 2.2-4.9 V vs. Li/Li <superscript>+</superscript> LiNi <subscript>0.5</subscript> Mn <subscript>1.5</subscript> O <subscript>4</subscript> with cubic spinel type structure demonstrates the capacity of 230 mAh·g <superscript>-1</superscript> associated with three first-order phase transitions with significant total volume change of 8.1%. The Li <subscript>2</subscript> Ni <subscript>0.5</subscript> Mn <subscript>1.5</subscript> O <subscript>4</subscript> material exhibits similar capacity value and subsequence of the phase transitions of the spinel phase, although the fraction of the spinel-type phase in this material does not exceed 30 wt.%. The main component of Li <subscript>2</subscript> Ni <subscript>0.5</subscript> Mn <subscript>1.5</subscript> O <subscript>4</subscript> is Li-rich layered oxide Li(Li <subscript>0.28</subscript> Mn <subscript>0.64</subscript> Ni <subscript>0.08</subscript> )O <subscript>2</subscript> , which provides nearly half of the capacity with very small unit cell volume change of 0.7%. Lower mechanical stress associated with Li (de)intercalation provides better cycling stability of the spinel-layered complex materials and makes them more perspective for practical applications compared to the single-phase LiNi <subscript>0.5</subscript> Mn <subscript>1.5</subscript> O <subscript>4</subscript> high-voltage cathode material.
Details
- Language :
- English
- ISSN :
- 2079-4991
- Volume :
- 11
- Issue :
- 6
- Database :
- MEDLINE
- Journal :
- Nanomaterials (Basel, Switzerland)
- Publication Type :
- Academic Journal
- Accession number :
- 34064226
- Full Text :
- https://doi.org/10.3390/nano11061368