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Adducts of the Parent Boraphosphaketene H 2 BPCO and their Decarbonylative Insertion Chemistry.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2021 Jun 07; Vol. 60 (24), pp. 13666-13670. Date of Electronic Publication: 2021 May 02. - Publication Year :
- 2021
-
Abstract
- The first examples of Lewis base adducts of the parent boraphosphaketene (H <subscript>2</subscript> B-PCO) and their cyclodimers are prepared. One of these adducts is shown to undergo mild decarbonylation and phosphinidene insertion into a B-C bond of a borole, forming very rare examples of 1,2-phosphaborinines, B/P isosteres of benzene. The strong donor properties of these 1,2-phosphaborinines are confirmed by the synthesis of their π complexes with the Group 6 metals.<br /> (© 2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 60
- Issue :
- 24
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 33843132
- Full Text :
- https://doi.org/10.1002/anie.202103521