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Zero-valent ML 2 complexes of group 10 metals supported by terphenyl phosphanes.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2021 Mar 28; Vol. 57 (25), pp. 3083-3086. Date of Electronic Publication: 2021 Mar 03. - Publication Year :
- 2021
-
Abstract
- Bulky terphenyl phosphane ligands PMe <subscript>2</subscript> Ar' (Ar' = terphenyl group) facilitate the isolation of zero-valent bis-phosphane complexes of nickel, palladium and platinum. The former show coordination numbers greater than two in the solid state due to the existence of Ni-C <subscript>arene</subscript> interactions with the terphenyl fragment.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 57
- Issue :
- 25
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 33656041
- Full Text :
- https://doi.org/10.1039/d1cc00676b