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A simple synthesis of [RuCl 2 (NHC)(p-cymene)] complexes and their use in olefin oxidation catalysis.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2021 Mar 21; Vol. 50 (11), pp. 3959-3965. Date of Electronic Publication: 2021 Mar 01. - Publication Year :
- 2021
-
Abstract
- A simple and efficient synthetic route to [RuCl <subscript>2</subscript> (NHC)(p-cymene)] and [Ru(CO <subscript>3</subscript> )(NHC)(p-cymene)] complexes making use of a weak base, under aerobic conditions, is reported. This method enables access to a series of NHC-ruthenium compounds with moderate to good yields under mild conditions. The Ru pre-catalysts were successfully used in olefin oxidation catalysis at low catalyst loading and reach complete conversion in short times.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 50
- Issue :
- 11
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 33646238
- Full Text :
- https://doi.org/10.1039/d1dt00030f