Chemistry of Atmospheric Fine Particles During the COVID-19 Pandemic in a Megacity of Eastern China.

Air pollution in megacities represents one of the greatest environmental challenges. Our observed results show that the dramatic NO _x decrease (77%) led to significant O ₃ increases (a factor of 2) during the COVID-19 lockdown in megacity Hangzhou, China. Model simulations further demonstrate large increases of daytime OH and HO ₂ radicals and nighttime NO ₃ radical, which can promote the gas-phase reaction and nocturnal multiphase chemistry. Therefore, enhanced NO ₃ ^- and SO ₄ ^2- formation was observed during the COVID-19 lockdown because of the enhanced oxidizing capacity. The PM _2.5 decrease was only partially offset by enhanced aerosol formation with its reduction reaching 50%. In particular, NO ₃ ^- decreased largely by 68%. PM _2.5 chemical analysis reveals that vehicular emissions mainly contributed to PM _2.5 under normal conditions in Hangzhou. Whereas, stationary sources dominated the residual PM _2.5 during the COVID-19 lockdown. This study provides evidence that large reductions in vehicular emissions can effectively mitigate air pollution in megacities.
Competing Interests: The authors declare that they have no conflicting interest.
(© 2020. The Authors.)