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Mid-Infrared Quartz-Enhanced Photoacoustic Sensor for ppb-Level CO Detection in a SF 6 Gas Matrix Exploiting a T-Grooved Quartz Tuning Fork.
- Source :
-
Analytical chemistry [Anal Chem] 2020 Oct 20; Vol. 92 (20), pp. 13922-13929. Date of Electronic Publication: 2020 Oct 01. - Publication Year :
- 2020
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Abstract
- An optical sensor for highly sensitive detection of carbon monoxide (CO) in sulfur hexafluoride (SF <subscript>6</subscript> ) was demonstrated by using the quartz-enhanced photoacoustic spectroscopy technique. A spectrophone composed of a custom 8 kHz T-shaped quartz tuning fork with grooved prongs and a pair of resonator tubes, to amplify the laser-induced acoustic waves, was designed aiming to maximize the CO photoacoustic response in SF <subscript>6</subscript> . A theoretical analysis and an experimental investigation of the influence of SF <subscript>6</subscript> gas matrix on spectrophone resonance properties for CO detection have been provided, and the performances were compared with the standard air matrix. A mid-infrared quantum cascade laser with a central wavelength at 4.61 μm, resonant with the fundamental band of CO, and an optical power of 20 mW was employed as the light excitation source. A minimum detection limit of 10 ppb at 10 s of integration time was achieved, and a sensor response time of ∼3 min was measured.
Details
- Language :
- English
- ISSN :
- 1520-6882
- Volume :
- 92
- Issue :
- 20
- Database :
- MEDLINE
- Journal :
- Analytical chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 32962343
- Full Text :
- https://doi.org/10.1021/acs.analchem.0c02772