Back to Search
Start Over
Engineering macrocyclic high performance pentagonal bipyramidal Dy(iii) single-ion magnets.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Oct 14; Vol. 56 (80), pp. 12037-12040. Date of Electronic Publication: 2020 Sep 09. - Publication Year :
- 2020
-
Abstract
- We generate a new air-stable pseudo-D <subscript>5h</subscript> Dy(iii) Single-Molecule Magnet (U <subscript>eff</subscript> = 1108 K, T <subscript>B</subscript> = 14 K) by combining a weak equatorial ligand field from a macrocyclic L <superscript>N5</superscript> ligand with a strong axial ligand field. Based on our synthetic blueprint, we use ab initio calculations to show the vast scope for macrocyclic engineering of magnetic anisotropy.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 56
- Issue :
- 80
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 32902527
- Full Text :
- https://doi.org/10.1039/d0cc04559d