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The C3-H Bond Functionalization of Quinoxalin-2(1 H )-Ones With Hypervalent Iodine(III) Reagents.

Authors :
Tan Y
Wang J
Zhang HY
Zhang Y
Zhao J
Source :
Frontiers in chemistry [Front Chem] 2020 Aug 03; Vol. 8, pp. 582. Date of Electronic Publication: 2020 Aug 03 (Print Publication: 2020).
Publication Year :
2020

Abstract

The modification of quinoxalin-2(1 H )-ones via direct C-H bond functionalization has begun to receive widespread attention, due to quinoxalin-2(1 H )-one derivatives' various biological activities and pharmaceutical properties. This mini review concentrates on the accomplishments of arylation, trifluoromethylation, alkylation, and alkoxylation of quinoxalin-2(1 H )-ones with hypervalent iodine(III) reagents as reaction partners or oxidants. The reaction conditions and mechanisms are compared and discussed in detail.<br /> (Copyright © 2020 Tan, Wang, Zhang, Zhang and Zhao.)

Details

Language :
English
ISSN :
2296-2646
Volume :
8
Database :
MEDLINE
Journal :
Frontiers in chemistry
Publication Type :
Academic Journal
Accession number :
32850624
Full Text :
https://doi.org/10.3389/fchem.2020.00582