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Activated carbon production from industrial yeast residue to boost up circular bioeconomy.

Authors :
Modesto HR
Lemos SG
Dos Santos MS
Komatsu JS
Gonçalves M
Carvalho WA
Carrilho ENVM
Labuto G
Source :
Environmental science and pollution research international [Environ Sci Pollut Res Int] 2021 May; Vol. 28 (19), pp. 24694-24705. Date of Electronic Publication: 2020 Aug 15.
Publication Year :
2021

Abstract

This work aims to obtain activated carbon (AC) from yeast residue to boost up bioeconomy. In this way, carbon was prepared from yeast biomass produced by the ethanol industry and after beta-glucan extraction. Carbon was activated with CO <subscript>2</subscript> , water vapor, and a combination of both using an experimental design. The best conditions to produce AC were activation with CO <subscript>2</subscript> for 30 min at 850 °C and CO <subscript>2</subscript> flow of 0.09 L/min, set by experimental design and desirability function to optimize the yield, surface area, and microporosity. Thus, for physical activation with water vapor employing the optimized conditions, it was possible to achieve a yield of 56.6% (m/m) for AC with 1144 m <superscript>2</superscript> /g of surface area and mean micropore volume of 0.53 cm <superscript>3</superscript> /g. The maximum AC surface area reached 1616 ± 567 m <superscript>2</superscript> /g with a yield of 21 ± 1%. The prepared ACs were characterized by elemental analysis, X-ray diffractometry, infrared spectroscopy, thermogravimetry analysis, pH <subscript>PZC</subscript> , and potentiometric titration to determine the main functional groups of sorption sites. The carbon obtained from the desirability condition was used to remove dipyrone from synthetic aqueous effluent with an experimental sorption capacity of 88 ± 4 mg/g, being the phenomenon described by the Freundlich isotherm model.

Details

Language :
English
ISSN :
1614-7499
Volume :
28
Issue :
19
Database :
MEDLINE
Journal :
Environmental science and pollution research international
Publication Type :
Academic Journal
Accession number :
32803592
Full Text :
https://doi.org/10.1007/s11356-020-10458-z