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A metastable Ru III azido complex with metallo-Staudinger reactivity.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Sep 15; Vol. 56 (73), pp. 10738-10741. - Publication Year :
- 2020
-
Abstract
- The metastable purple [(Py5Me2)RuIII(N3)]2+ ion reacts with PPh3 at room temperature to form the phosphinimine complex [(Py5Me2)RuII(N(H)PPh3)]2+ and free [H2NPPh3]+ in a combined 23% conversion. Mechanistic studies suggest that this is the first metallo-Staudinger reaction of a late transition metal that bypasses the nitrido mechanism and instead utilizes a Ru-N[double bond, length as m-dash]N[double bond, length as m-dash]N-PPh3 phosphazide intermediate.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 56
- Issue :
- 73
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 32789338
- Full Text :
- https://doi.org/10.1039/d0cc04426a