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Overriding ortho selectivity by template assisted meta-C-H activation of benzophenones.

Authors :
Casali E
Kalra P
Brochetta M
Borsari T
Gandini A
Patra T
Zanoni G
Maiti D
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Jul 07; Vol. 56 (53), pp. 7281-7284. Date of Electronic Publication: 2020 Jun 01.
Publication Year :
2020

Abstract

An orthogonal selectivity for distal meta-C-H activation of benzophenone is acheived by overriding the inherent proximal ortho-selectivity through a template assisted metalation approach. This strategy has been successfully utilized in Pd-catalyzed regioselective C-C and C-Si bond formation.

Details

Language :
English
ISSN :
1364-548X
Volume :
56
Issue :
53
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
32478359
Full Text :
https://doi.org/10.1039/d0cc03172k