The impact of natural weathering and mining on heavy metal accumulation in the karst areas of the Pearl River Basin, China.

This paper presents the heavy metal content in river water, sediment and bedrock in the karst area of the Pearl River Basin in China to evaluate the long-term impact of natural weathering and mining on the ecological environment. The results show that Cd and As is 2-3 times more enriched within the carbonate bedrock of the Pearl River Basin compared to the upper continental crust (UCC), which is indicative of high geological background values. Within the river water of the upper reaches of the Diaojiang River (a tributary of the Pearl River), which flows through the Dachang super-large orefield, Zn, As, Cd and Sb exceeds the environmental quality standards for surface water (WQS) by more than an order of magnitude. Among these, Zn and Cd sharply decreases to within the WQS in the lower reaches of the river, but the content of As and Sb in the estuary is still several times higher than the WQS. Cd in the sediments of the small carbonate watersheds and in the mainstream of the Pearl River only present a low-moderate ecological risk. In contrast, severe heavy metal pollution of the sediments of the Diaojiang River Basin is observed. Even in the lower reaches, remote from the mining area, the content of Pb, Zn, As and Cd in the sediments is still two orders of magnitude higher than the soil background values. The content of both Cd and As presents a very high ecological risk, indicating that under the cumulative effect of high geological background values and mining, full restoration of the ecological environment in the Diaojiang River Basin is a complex and long-term process.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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