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Toward Easy-to-Assemble, Large-Area Smart Windows: All-in-One Cross-Linked Electrochromic Material and Device.

Toward Easy-to-Assemble, Large-Area Smart Windows: All-in-One Cross-Linked Electrochromic Material and Device.

Authors :
Zheng R
Wang Y
Pan J
Malik HA
Zhang H
Jia C
Weng X
Xie J
Deng L
Source :
ACS applied materials & interfaces [ACS Appl Mater Interfaces] 2020 Jun 17; Vol. 12 (24), pp. 27526-27536. Date of Electronic Publication: 2020 Jun 04.
Publication Year :
2020

Abstract

Conventional electrochromic devices with a sandwich structure consist of multiple interfaces, which enhance electron trapping on the interfaces. Furthermore, crack generation in the electrochromic layer is inevitable due to repeated ion insertion and extraction during the service process. These problems increase the fabrication complexity and lead to poor performance and stability, which are severely limiting and prime concerns for the future development of the electrochromism field. Here, a strategy of synthesizing an all-in-one self-healing electrochromic material, TAFPy-MA, is presented, which has been utilized for the fabrication of a high-reliability, large-scale, and easy-assembly smart electrochromic window. The all-in-one self-healing electrochromic material can undergo in situ redox reactions with Li <superscript>+</superscript> ions to reduce resistance transfer and avoid interface obstacles, and the reversible Diels-Alder cross-linking network structure can heal the cracks to improve the reliability of the electrochromic layer. High ion diffusivity (1.13 × 10 <superscript>-5</superscript> cm <superscript>2</superscript> s <superscript>-1</superscript> ), rapid color switching (3.9/3.7 s), high coloration efficiency (413 cm <superscript>2</superscript> C <superscript>-1</superscript> ), excellent stability (sustains 88.7% after 1000 cycles) and reliability (crack can be healed in 110 s), and large-scale smart windows (30 × 35 cm <superscript>2</superscript> ) are achieved using the all-in-one electrochromic material, which exhibits fascinating and promising features for a wide range of applications in buildings, airplanes, etc.

Details

Language :
English
ISSN :
1944-8252
Volume :
12
Issue :
24
Database :
MEDLINE
Journal :
ACS applied materials & interfaces
Publication Type :
Academic Journal
Accession number :
32423198
Full Text :
https://doi.org/10.1021/acsami.0c02337