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Phase Transformations and Photocatalytic Activity of Nanostructured Y 2 O 3 /TiO 2 -Y 2 TiO 5 Ceramic Such as Doped with Carbon Nanotubes.

Authors :
Kozlovskiy AL
Zhumatayeva IZ
Mustahieva D
Zdorovets MV
Source :
Molecules (Basel, Switzerland) [Molecules] 2020 Apr 22; Vol. 25 (8). Date of Electronic Publication: 2020 Apr 22.
Publication Year :
2020

Abstract

This work is devoted to the study of phase transition processes in nanostructured ceramics of the Y <subscript>2</subscript> O <subscript>3</subscript> /TiO <subscript>2</subscript> -Y <subscript>2</subscript> TiO <subscript>5</subscript> type doped with carbon nanotubes as a result of thermal annealing, as well as to the assessment of the prospects of the effect of phase composition on photocatalytic activity. By the method of X-ray phase analysis, it was found that an increase in the annealing temperature leads to the formation of the orthorhombic phase Y <subscript>2</subscript> TiO <subscript>5</subscript> , as well as structural ordering. Based on the obtained UV spectra, the band gap was calculated, which varies from 2.9 eV (initial sample) to 2.1 eV (annealed at a temperature of 1000 °C). During photocatalytic tests, it was established that the synthesized nanostructured ceramics Y <subscript>2</subscript> O <subscript>3</subscript> /TiO <subscript>2</subscript> -Y <subscript>2</subscript> TiO <subscript>5</subscript> doped CNTs show a fairly good photocatalytic activity in the range of 60-90% decomposition of methyl orange.

Details

Language :
English
ISSN :
1420-3049
Volume :
25
Issue :
8
Database :
MEDLINE
Journal :
Molecules (Basel, Switzerland)
Publication Type :
Academic Journal
Accession number :
32331375
Full Text :
https://doi.org/10.3390/molecules25081943