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A HF Loaded Lewis-Acidic Aluminium Chlorofluoride for Hydrofluorination Reactions.

Authors :
Kervarec MC
Kemnitz E
Scholz G
Rudić S
Braun T
Jäger C
Michalchuk AAL
Emmerling F
Source :
Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2020 Jun 05; Vol. 26 (32), pp. 7314-7322. Date of Electronic Publication: 2020 May 26.
Publication Year :
2020

Abstract

The very strong Lewis acid aluminium chlorofluoride (ACF) was loaded with anhydrous HF. The interaction between the surface of the catalyst and HF was investigated using a variety of characterization methods, which revealed the formation of polyfluorides. Moreover, the reactivity of the HF-loaded ACF towards the hydrofluorination of alkynes was studied.<br /> (© 2020 The Authors. Published by Wiley-VCH Verlag GmbH & Co. KGaA.)

Details

Language :
English
ISSN :
1521-3765
Volume :
26
Issue :
32
Database :
MEDLINE
Journal :
Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Type :
Academic Journal
Accession number :
32315479
Full Text :
https://doi.org/10.1002/chem.202001627