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Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction.
- Source :
-
Dalton transactions (Cambridge, England : 2003) [Dalton Trans] 2020 May 07; Vol. 49 (17), pp. 5440-5444. Date of Electronic Publication: 2020 Apr 21. - Publication Year :
- 2020
-
Abstract
- Two new metal phosphates, namely, Zn(HPO <subscript>4</subscript> )(C <subscript>6</subscript> H <subscript>11</subscript> NO <subscript>2</subscript> ) (1) and (C <subscript>5</subscript> H <subscript>10</subscript> NO <subscript>2</subscript> )Ga <subscript>4</subscript> (PO <subscript>4</subscript> ) <subscript>4</subscript> F·3H <subscript>2</subscript> O (2), were prepared under surfactant-thermal conditions. Single-crystal X-ray diffraction analyses reveal that compound 1 has a zigzag-chain structure decorated with homoproline and compound 2 has a three-dimensional zeolite-like structure templated by proline. Notably, compound 2 remains stable in both boiling water and aqueous solutions with a pH range of 2-12. It shows a proton conductivity of 8.89 × 10 <superscript>-4</superscript> S cm <superscript>-1</superscript> at 85 °C and 95% relative humidity.
Details
- Language :
- English
- ISSN :
- 1477-9234
- Volume :
- 49
- Issue :
- 17
- Database :
- MEDLINE
- Journal :
- Dalton transactions (Cambridge, England : 2003)
- Publication Type :
- Academic Journal
- Accession number :
- 32314753
- Full Text :
- https://doi.org/10.1039/d0dt00966k