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Synthesis of α-CF 3 -substituted E-dehydroornithine derivatives via copper(i)-catalyzed hydroamination of allenes.
- Source :
-
Organic & biomolecular chemistry [Org Biomol Chem] 2020 May 06; Vol. 18 (17), pp. 3274-3280. - Publication Year :
- 2020
-
Abstract
- An efficient synthetic approach to novel α-CF3-substituted E-dehydroornithine derivatives and their phosphorus analogues has been developed via the Cu(i)-catalyzed hydroamination of trifluoromethyl-containing α-allenyl-α-aminocarboxylates and α-allenyl-α-aminophosphonates with primary and secondary amines.
Details
- Language :
- English
- ISSN :
- 1477-0539
- Volume :
- 18
- Issue :
- 17
- Database :
- MEDLINE
- Journal :
- Organic & biomolecular chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 32307483
- Full Text :
- https://doi.org/10.1039/d0ob00580k