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Nitroprusside as a promising building block to assemble an organic-inorganic hybrid for thermo-responsive switching materials.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 May 21; Vol. 56 (41), pp. 5488-5491. - Publication Year :
- 2020
-
Abstract
- We present a new hybrid compound, namely (Me2NH2)[KFe(CN)5(NO)], possessing a unique nitroprusside-based inorganic host framework in 4-connected sra topology encapsulating organic guest cations. The flexible host-guest hydrogen bonds and synchronously deformed inorganic framework give rise to thermal-responsive switching behaviours on both thermal expansion and nonlinear optical properties during the phase transition at around room temperature.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 56
- Issue :
- 41
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 32297617
- Full Text :
- https://doi.org/10.1039/d0cc01877e