Back to Search
Start Over
Silver-promoted synthesis of vinyl sulfones from vinyl bromides and sulfonyl hydrazides in water.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Apr 30; Vol. 56 (34), pp. 4688-4691. Date of Electronic Publication: 2020 Mar 25. - Publication Year :
- 2020
-
Abstract
- The synthesis of vinyl sulfones via silver-promoted cross-coupling of vinyl bromides with sulfonyl hydrazides was realized. Water was used as the sole solvent. Multisubstituted vinyl sulfones were easily prepared with excellent alkyl group tolerance. A mechanism involving nucleophilic attack of a sulfinate anion was proposed.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 56
- Issue :
- 34
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 32211708
- Full Text :
- https://doi.org/10.1039/d0cc00784f