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Benchtop access to anhydrous actinide N-donor coordination complexes using ionic liquids.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2020 Apr 18; Vol. 56 (30), pp. 4232-4235. Date of Electronic Publication: 2020 Mar 17. - Publication Year :
- 2020
-
Abstract
- By dehydrating actinide salts with an ionic liquid containing a common anion and subsequent reaction with N-heterocyclic ligands, we challenge the concept that actinides prefer O- over N-donors; rather the acidic hydrogen atoms of protic solvents hinder the formation of more elusive f-element N-donor coordination complexes.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 56
- Issue :
- 30
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 32182311
- Full Text :
- https://doi.org/10.1039/c9cc09852f