Back to Search Start Over

Highly fluorescent carbon dots derived from Mangifera indica leaves for selective detection of metal ions.

Authors :
Singh J
Kaur S
Lee J
Mehta A
Kumar S
Kim KH
Basu S
Rawat M
Source :
The Science of the total environment [Sci Total Environ] 2020 Jun 10; Vol. 720, pp. 137604. Date of Electronic Publication: 2020 Feb 26.
Publication Year :
2020

Abstract

In this study, we report an inexpensive, green, and one-pot synthesis method for highly fluorescent carbon quantum dots (CQDs) using mango (Mangifera indica: M. indica) leaves to develop an efficient sensing platform for metal ions. The CQDs synthesized from M. indica leaves via pyrolysis treatment at 300 °C for 3 h were characterized by various spectroscopic and electron microscopy techniques for their structural, morphological, and optical properties. Accordingly, the synthesized CQDs showed an absorption peak at 213 nm to confirm the p-p* transition of the carbon core state, while the CQD particles were spherical with a size less than 10 nm. The prepared CQDs showed excellent fluorescent properties with blue emission spectra (around 525 nm) upon excitation at 435 nm. The synthesized CQDs had the prodigious sensing potential to detect Fe <superscript>2+</superscript> ions in water with a limit of detection of 0.62 ppm. Additionally, their sensing capability was tested using a real sample (e.g., Livogen tablet). Moreover, the synthesized CQDs showed substantial stability over a long period (three months). Thus, this study provides an inexpensive and facile method for CQD-based sensing of Fe <superscript>2+</superscript> ions with a photoluminescence quenching mechanism.<br />Competing Interests: Declaration of competing interest This experimental research work is original and was carried out at the authors' institute. This work possesses no intellectual or financial conflict of interests.<br /> (Copyright © 2020 Elsevier B.V. All rights reserved.)

Details

Language :
English
ISSN :
1879-1026
Volume :
720
Database :
MEDLINE
Journal :
The Science of the total environment
Publication Type :
Academic Journal
Accession number :
32143054
Full Text :
https://doi.org/10.1016/j.scitotenv.2020.137604