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Metal-Organic Coordination versus Hydrogen Bonding: Highly Efficient Templated Photocycloadditions of Trisubstituted Isomeric Olefins in the Solid State.
- Source :
-
ChemPlusChem [Chempluschem] 2016 Aug; Vol. 81 (8), pp. 893-898. Date of Electronic Publication: 2016 Jul 29. - Publication Year :
- 2016
-
Abstract
- Trisubstituted olefins are reactants in template-directed, solid-state [2+2] photocycloaddition reactions. Whereas hydrogen-bond-based templates afford crystalline assemblies with olefins that are photostable, Ag <superscript>I</superscript> coordination results in carbon-carbon double bonds that react stereoselectively and result in quantitative yield.<br /> (© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 2192-6506
- Volume :
- 81
- Issue :
- 8
- Database :
- MEDLINE
- Journal :
- ChemPlusChem
- Publication Type :
- Academic Journal
- Accession number :
- 31968836
- Full Text :
- https://doi.org/10.1002/cplu.201600261