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Transition-Metal-Like Catalysis with a Main-Group Element: Bismuth-Catalyzed C-F Coupling of Aryl Boronic Esters.
- Source :
-
Angewandte Chemie (International ed. in English) [Angew Chem Int Ed Engl] 2020 May 25; Vol. 59 (22), pp. 8328-8330. Date of Electronic Publication: 2020 Jan 09. - Publication Year :
- 2020
-
Abstract
- The main-group age: The past decade has revealed main-group-element compounds that display transition-metal-like reactivity in stoichiometric and even catalytic transformations. Cornella and co-workers have now reported a bismuth complex that catalyzes fluoroarene formation from aryl boronate esters, a reaction that is almost unprecedented in transition-metal catalysis.<br /> (© 2020 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.)
Details
- Language :
- English
- ISSN :
- 1521-3773
- Volume :
- 59
- Issue :
- 22
- Database :
- MEDLINE
- Journal :
- Angewandte Chemie (International ed. in English)
- Publication Type :
- Academic Journal
- Accession number :
- 31916671
- Full Text :
- https://doi.org/10.1002/anie.201914729