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Photocatalytic Isocyanide-Based Multicomponent Domino Cascade toward the Stereoselective Formation of Iminofurans.
- Source :
-
The Journal of organic chemistry [J Org Chem] 2020 Feb 21; Vol. 85 (4), pp. 1981-1990. Date of Electronic Publication: 2020 Jan 10. - Publication Year :
- 2020
-
Abstract
- A visible-light-promoted three-component isocyanide-based synthesis of iminofurans is herein reported. The reaction proved to be general in scope and proceeds through a triple domino process. Control experiments with <superscript>18</superscript> O-labeled water and TEMPO provided key mechanistic insights for delineating the reactivity paradigms crucial to design efficient photoredox isocyanide-based domino transformations.
Details
- Language :
- English
- ISSN :
- 1520-6904
- Volume :
- 85
- Issue :
- 4
- Database :
- MEDLINE
- Journal :
- The Journal of organic chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 31880934
- Full Text :
- https://doi.org/10.1021/acs.joc.9b02709