Modes interplay and dynamics in the second harmonic generation of plasmonic nanostructures.

The full wave surface integral equation computation of the second harmonic generation (SHG) dynamics for metal spheres and nanorods - presented as multimedia files - is performed to reveal the dynamics of the modes supported by the nanostructure. We demonstrate that the interplay between different modes controls the nonlinear response and that the size-induced redshift of the eigenmodes can be manipulated by adjusting the nanostructure geometry, so that the SHG signal can be boosted at specified frequencies. We show that the SHG radiation is not necessarily quadrupolar in spherical nanoparticles, as it is often assumed. Finally, we introduce an efficient way to reduce the SHG calculation time.